“Twilight’s” Kristen Stewart exudes sexy sophistication in the UK edition of Elle magazine. The photo spread shows her with a ’60s style bouffant and dark eyeliner wearing one of Jackie O’s favorite designers, Valentino.

Stewart is most often photographed in her preferred jeans, tee-shirts and hoodie jacket with a pair of chucks. But in a series of high-fashion shoots for magazine she epitomizes glamour.

Kristen Stewart Sizzles in Valentino
(Click Photos to Enlarge!)

She was just named Glamour magazine’s best dressed woman, even beating out fashion plate Victoria Beckham, who has her own line of clothes.

In the UK shoot, titled “Out of the Twilight,” she wears Valentino, Miu Miu, and shoes by Marc Jacobs.

Although Kristen looks stunning in high fashion, she’s the queen of anti-fashion. Even Hollywood stylists refuse to work with her, because of her do-it-yourself approach.

Kristen, however, seems to be paying more attention to fashion. She made the scene at Paris Fashion Week and has worn clothes by Balenciaga, Chanel, J Mendel and Roberto Cavalli at various events this year.

Glamour magazine noted Kristen’s growth from “awkward teen to style queen” and for always being “effortlessly on-trend.” She and boyfriend Robert Pattinson were also named best dressed couple.

Click here to find out why Kristen hates Chucky dolls!

Last December, Stewart, joined the likes of British royal Kate Middleton, the Duchess of Cambridge, joined the best dressed list of the UK edition of Vogue.

Check out her new cover and and shots from the magazine.